Tectonic history of the ophiolitic rocks of the highland border fracture zone, Scotland: Stable isotope evidence from rock-fluid interactions during obduction

The mafic and ultramafic rocks of the Highland Border Fracture Zone are ophiolitic remnants of a pre-Grampian marginal basin that opened either within, or to the north of, the Dalradian sedimentary pile. Closure of the basin was achieved through a combination of northerly-directed subduction, and obduction of ophiolitic thrust-slices onto the basin's southern margin. During the early stages of obduction, young hot peridotite slabs were thrust over the cold upper surfaces of lower thrust sheets, producing a dynamothermal metamorphic sole. Serpentinisation of these peridotites, whilst they were still cooling, occurred in a near-surface position through the interaction of meteoric waters. Subsequently, the ophiolitic thrust-sheets, which comprise lizardite serpentinites, spilitic pillow lavas, and aureole rocks, were thrust over the uppermost Dalradian nappes which were themselves being expelled southwards, thereby accommodating basement shortening. Grampian regional metamorphism of the nappe pile and overlying Highland Border Suite ophiolitic thrust sheets, produced greenschist metaspilites from the spilitic pillow lavas, induced minor retrogression in the aureole rocks, and caused the lizardite in the serpentinites to be recrystallised and replaced by antigorite. The Highland Border Suite greenschist facies metamorphic fluids were D-enriched compared with low-grade Dalradian metamorphic waters, and may have been mixtures of the latter and D-rich dehydration fluids released from the mafic rocks during dynamothermal metamorphism. Brittle fracturing and shearing in the serpentinites were responses to late deformation at different crustal levels during the final stages of emplacement, which involved gravity-sliding as well as downbending of the Dalradian nappes and ophiolitic thrust-sheets against the elevated Midland Valley block.