On the CN (0, 0) spectrum of Comet Mrkos 1957d

We have carried out an analysis of the (0, 0) vibrational band of the CN molecule in Comet Mrkos 1957d, including the effect of collisions. We found that the sum of the squares of the residuals can be reduced by a factor of ten, if collisions account for 46±3% of the population of the lower level. A rotational temperature can be assigned to the cometary gas. The best value found was 410±40 K. The best fit for the constantR ₁ was (1.07±0.10)×10^–4. The velocity of the comet was left as a free parameter. We found for it a value of 34.38±0.10 km s^–1. This result is in disagreement with the nuclear orbital velocity of 34.74 km s^–1. The discrepancy can be explained, if the CN molecules are ejected from the cometary nucleus preferentially in the sunward direction, with a mean velocity that corresponds to the above temperature.