The winter anomaly in ionospheric absorption and the D-region ion chemistry

A detailed analysis of the D-region ion composition measurements performed by Zbinden et al. (1975), during a winter day of high ionospheric absorption, has been carried out. The study examines the interactive mesosphere-D-region processes which occur in such anomalous conditions and their implication for water cluster ion chemistry. Two clustering regimes for NO⁺ have been observed in the data. Association with N₂ is identified as the dominant process below 76 km. Between 76 and 78 km altitude the effective loss rate of NO⁺ drops by two orders of magnitude. Above 77 km, the three-body reaction NO⁺ + CO₂+M→NO⁺CO₂+M seems to be the main NO⁺ loss. A mesospheric temperature profile could be derived from the ion composition data. This indicates the presence of a strong inversion above 76 km altitude. The wavelike structure obtained, is shown to be consistent with in situ winter temperature measurements. The sharp suppression of the N₂ association reaction could, thus, be explained by an increase in the collisional break-up of the NO⁺N₂ ion because of the enhanced temperature. In conclusion, our study indicates that, besides the increase in the production of NO⁺ and O₂⁺, due to an enhancement in the minor ionizable constituents, an additional thermal mesosphere-D-region interaction seems necessary to explain this winter anomalous ion composition data.