Some aspects of condensation in clouds

Several general features of nucleation characteristics of low density cosmic clouds are discussed. These are: (1) tendency for metastable condensates to form, (2) non-occurrence of nominal refractory molecule in the gas, (3) a strong temperature dependence of condensation at relatively low temperatures, and (4) significant vibrational disequilibrium in cosmic clouds. These support previous analyses by the author which indicate that equilibrium calculations have restricted applicability. A kinetic treatment of condensation is required for cosmic grains and the possibility of formulating such an analysis is pointed out.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium, held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.