Multivariate analysis to investigate Cl distribution in rocks from different settings

Chlorine concentration has been determined by chemical methods in 97 samples of basic rocks collected at Etna volcano (Sicily, Southern Italy), Sao Miguel (Azores Islands), and Lanzarote (Canary Islands). The samples have been processed together with data related to specific magmatic and tectonic conditions, drawn from the literature. Thus, the contents of SiO₂, K₂O, and P₂O₅ of 228 samples have been used to investigate Cl distribution in the considered environments, using principal component analysis. The log-centered variance-covariance matrix has been processed in order to overcome the closure constraints. The results indicate that a clear distinction between continental and oceanic regions can be obtained in the components space. A preliminary discriminant diagram involving chlorine thus can be proposed.