Residues of toxaphene decrease in estuarine fish after removal of contaminated sediments |
| |
Authors: | Keith A Maruya Leo Francendese Randall O Manning |
| |
Institution: | 1. Skidaway Institute of Oceanography, 10 Ocean Science Circle, 31411, Savannah, Georgia 3. U.S. Environmental Protection Agency, 61 Forsyth Street, 30303, Atlanta, Georgia 4. Georgia Department of Natural Resources, 745 Gaines School Road, 30605, Athens, Georgia
|
| |
Abstract: | To determine if toxaphene residues in edible fish tissue decreased after removal of contaminated sediments from an estuarine
site in 1999, 51 composite samples representing six finfish species were collected in 2001 and analyzed using gas chromatography
with electron capture and negative ion mass spectrometric detection. The grand mean total toxaphene residue concentration
on a wet weight basis (ΣTOXwet) was 1,400 ± 3,500 ng g−1 (range: < 18 to 18,000 ng g−1) and was positively correlated with extractable lipid. On a lipid basis, the mean ΣTOXlip was 26 ± 33 μg g1, which decreased with increasing distance from the study site. Although benthically-oriented species, such as spot (Leiostomus xanthurus) and striped mullet (Mugil cephalus), exhibited higher mean ΣTOXwet than those of higher trophic level fish, mean ΣTOXlip were not significantly different among species. The grand mean ΣTOX for 2001 was 3.8 (wet) and 2.6 (lipid) times less than
corresponding preremedial action (1997) concentrations, suggesting that bioavailable toxaphene residues in this system have
been reduced. Forage species, such as croaker (Micropogonias undulatus), mullet, and spot, preferentially accumulate toxaphene residues in this system and may serve as vectors of organochlorine
contaminants in the estuarine and coastal ocean food web. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|