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Distribution and Fluxes of Calcium Carbonatealong the Continental Margin in the Gulf of Biscay
Authors:Roland Wollast  Lei Chou
Abstract:Compositions of major components in suspended matter,collected by centrifugation, in situ pumping andsediment traps, in the Gulf of Biscay during the OMEXproject were determined and compared. The resultsshow a strong and rapid decrease in the concentrationof biogenic fraction in the upper 200 m of the watercolumn which may be attributed to the preferentialremoval of this component due to the production offaecal pellets and to the formation of marine snow. Concurrent decrease with depth of the organic andinorganic carbon contents demonstrate the importanceof the respiration of organic matter and thedissolution of calcium carbonate in the oceanic carboncycling. Lithogenic and carbonate fluxes across thecontinental slope in the Goban Spur area wereevaluated based on sediment trap records. The rate ofproduction of calcium carbonate in the surface waters(100 g CaCO3 m-2y-1), deduced from theprimary production measurements, is much largercompared to the fluxes of this component observed inthe sediment traps (5–21 g CaCO3 m-2y-1)and to its rate of burial (9–31 gCaCO3 m-2y-1). It strongly suggeststhe occurrence of carbonate dissolution, even inwaters oversaturated with respect to the mineral phaseconsidered. This is likely to be associated with therespiration of organic matter within the faecalpellets, or at the surface of biogenic calcite oraragonite
Keywords:carbonate dissolution  suspended matter  particulate organic matter  inorganic carbon cycle  vertical fluxes  lateral transport  sediment traps  Gulf of Biscay
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