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Determination of carbon dioxide solubility in oil during interaction with a compound gaseous phase
Authors:A. D. Grichuk  T. A. Kireeva  V. K. Utoplennikov
Affiliation:16452. Faculty of Geology, Moscow State University, Moscow, 119991, Russia
26452. OAO TNK-Nyagan, ul. Sibirskaya 10/1, Nyagan, 628183, Russia
Abstract:A thermodynamic method for the determination of the solubility of a mixture of carbon dioxide and hydrocarbon gases in oil is elaborated on the basis of stage-oil separation. A method for the calculation of Henry’s constants for gases that are dissolved in oil and their temperature extrapolation are shown. Effective thermodynamic properties are estimated for carbon dioxide and C1–C8 hydrocarbon gases dissolved in oil. A thermodynamic model that satisfactorily describes the separation of gas from oil is created and may be included in a more complex calculation model of carbonate scaling during the exploitation of oil deposits.
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