Implications of using broadband photometry for compositional remote sensing of icy objects

Water ice has such a low absorption coefficient at visual wavelengths (～0.01 cm^?1) that a very small amount of particulate material can significantly darken an icy surface. A variety of ice plus particle mixtures were studied to show that particulate contaminations of ～1% by weight (even 0.1% or less in some cases) in ice or frosts result in reflectance levels close to that of the contaminants. In a very clear ice (no bubbles) it is plausible to have a reflectance < 0.05 for particulate contaminations ～10^?7 by weight for submicron dark particles, such as carbon lampblack. Scattering conditions compete for domination with contaminants for control of visual reflectance, implying that the apparent reflectivity level and color of a surface is a poor indicator of ice content. A dark surface (e.g., albedo 0.05) does not necessarily imply that there us very little water ice present. Infrared JHK colors of water ice and other minerals, including ice-mineral mixtures, show that some orthopyroxenes can have JHK colors very similar to fine-grained water frosts. In general, it is possible that the JHK colors of an ice plus particulate mixture can fall anywhere in the classical J-H versus H-K diagram, thus the diagram cannot be used to distinguish a predominately “rock” surface from one which is predominantely ice for one specific case. An important exception is the case where both the J-H and H-K colors are ??0.2. It appears that such colors indicate a relatively pure icy surface. In some cases, the diagram might be used as a statistical tool to distinguish between the compositions of surfaces within a class of objects, but the validity of such comparisons decreases for different classes, such as the main-belt asteroids when compared to outer solar system satellites, where water ice is more stable.