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Surface changes on crystalline stones due to salt crystallisation
Authors:Patricia Vázquez  Ana Luque  Francisco J Alonso  Carlota M Grossi
Institution:1. Géosciences et Environnement, Université de Cergy-Pontoise, 5, Mail Gay-Lussac, Rue d’Eragny, Neuville-sur-Oise, 95031, Cergy-Pontoise, Cedex, France
2. Facultad de Geología, Universidad de Oviedo, Jesús Arias de Velasco s/n, 33005, Oviedo, Asturias, Spain
3. Facultad de Ciencias, Universidad de Granada, Fuentenueva s/n, 18002, Granada, Spain
4. School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
Abstract:This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness.
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