Dynamics of surface-air pollution during the passage of a cold front

The dynamics of meteorological parameters, of sodar data on the temperature stratification of the atmospheric boundary layer, and of surface contents of pollutants (nitrogen oxides, carbon monoxide, and ozone) during the passage over Moscow of a structurally complex prominent cold front are discussed. It is shown that the cold front passage is accompanied by stepwise increases in the NO, NO₂, and CO surface contents. A probable cause of this phenomenon is a quick entrainment of smoke plumes from high-altitude sources of pollution into the surface turbulent air near the frontal boundary. Intense advection of cold air at the rear of the cyclone can lead to the development of an unstable stratification in the atmospheric boundary layer even in the nighttime. Under these conditions, the minute-scale variability of contents of trace gases increases abruptly as compared to that occurring in the frontal zone of the cyclone prior to the passage of the front. This effect is statistically significant. The dynamics of surface ozone reflects an increase in its background concentrations in arctic air masses.