Impacts as sources of the exosphere on Mercury

Chemical processes associated with meteoroid bombardment of Mercury are considered. Meteoroid impacts lead to production of metal atoms as well as metal oxides and hydroxides in the planetary exosphere. By using quenching theory, the abundances of the main Na-, K-, Ca-, Fe-, Al-, Mg-, Si-, and Ti-containing species delivered to the exosphere during meteoroid impacts were estimated. Based on a correlation between the solar photo rates and the molecular constants of atmospheric diatomic molecules, photolysis lifetimes of metal oxides and SiO are estimated. Meteoroid impacts lead to the formation of hot metal atoms (0.2-0.4 eV) produced directly during impacts and of very hot metal atoms (1-2 eV) produced by the subsequent photolysis of oxides and hydroxides in the exosphere of Mercury. The concentrations of impact-produced atoms of the main elements in the exosphere are estimated relative to the observed concentrations of Ca, assumed to be produced mostly by ion sputtering. Condensation of dust grains can significantly reduce the concentrations of impact-produced atoms in the exosphere. Na, K, and Fe atoms are delivered to the exosphere directly by impacts while Ca, Al, Mg, Si, and Ti atoms are produced by the photolysis of their oxides and hydroxides. The chemistry of volatile elements such as H, S, C, and N during meteoroid bombardment is also considered. Our conclusions about the temperature and the concentrations of impact-produced atoms in the exosphere of Mercury may be checked by the Messenger spacecraft in the near future and by BepiColombo spacecraft some years later.