Pleistocene decalcification of Late Pliocene Red Crag shelly sands from Walton-on-the-Naze, England

Uppermost sands of the Red Crag at Walton-on-the-Naze (Essex) and elsewhere in East Anglia have been decalcified to iron-stained quartz sands. In contrast, lower sands are only minimally altered and contain aragonitic and calcitic shells. Aragonitic shells are slightly dissolved (chalkified), but calcitic shells are unaffected. Cementation is limited to an addition of iron oxides, now mainly haematite, which also coat carbonate grains. Abundant iron-oxide fines in the upper decalcified sands were liberated from the coatings of shells; shells that have since dissolved. The diagenetic nature of the contact between decalcified upper and unaffected lower sands is evident where it transects cross-bedding. The contact is knife-sharp, even smoothly truncating large shells, and is usually planar and subhorizontal. Shelly sands immediately beneath the boundary contain similar amounts of aragonitic material, as do sands further below. Locally the decalcification boundary has been contorted by cryoturbation, implying that carbonate dissolution was a Pleistocene event. Decalcification probably occurred when the area was affected by permafrost. Lower sands were cemented by ice and protected from dissolution. Upper sands were above the ice table and subject to chemically aggressive waters during summer thaws. Decalcification is believed to have taken place during an episode of climate amelioration when downward retreat of the ice table accompanied replacement of tundra by boreal forest. Highly acidic and podzolic soils developed, beneath which shell-carbonate dissolved. Sharp based decalcified zones in Lowestoft Till and Devensian deposits in other parts of England can also be attributed to dissolution associated with permafrost.