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Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)
Authors:Takuya Matsumoto  Masahiko Honda  Ian McDougall  Igor Yatsevich  Suzanne Y O'Reilly
Institution:Department of Earth and Space Science, Graduate School of Science, Osaka University, Toyonaka 560-0043, Osaka, Japan;;Research School of Earth Sciences, The Australian National University, Canberra ACT 0200, Australia;;Key Centre for Geochemical Evolution and Metallogeny of Continents (GEMOC), School of Earth Sciences, Macquarie University, Sydney, NSW 2109, Australia
Abstract:Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.
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