| Abstract: | Phase equilibrium modelling of a conformable sequence of supracristal lithologies from the Bushmanland Subprovince of the Namaqua–Natal Metamorphic Complex (South Africa) reveals a disparity of some 60–70°C in estimated peak metamorphic temperature. Aluminous metapelites were equilibrated at ~770–790°C, whereas two‐pyroxene granulite and garnet–orthopyroxene–biotite gneiss record distinctly higher conditions of ~830–850°C. Semi‐pelite and Mg–Al‐rich gneisses yield poorly constrained estimates that span the range derived from other lithologies. All samples record peak pressure of ~5–6 kbar, and followed a roughly isobaric heating path from andalusite‐bearing greenschist/lower amphibolite facies conditions through a tight clockwise loop at near‐peak conditions, followed by near‐isobaric cooling. The disparity in peak temperatures appears to be robust, as the low‐variance assemblages in all samples reflect well‐known melting reactions that only occur over narrow temperature intervals. The stable coexistence of both products and reactants of these melting reactions indicates that they did not go to completion before metamorphism waned. Calculated pressure–enthalpy diagrams show that the melting reactions are strongly endothermic and therefore buffer temperature while heat is consumed by melting. Because the respective reactions occur at distinct P–T conditions and have different reactant assemblages, individual lithologies are thermally buffered at different temperatures and to different degrees, depending on the occurrence and abundance of reactant minerals. Our calculations show that all lithologies received essentially the same suprasolidus heat budget of 19 ± 1 kJ/mol, which led to the manifestation of lower peak temperatures in the more fertile and strongly buffered aluminous metapelites compared with more refractory rock types. If little to no thermal communication is assumed, this implies that lithology exerts a first‐order control over the heating path and the peak temperature that can be attained for a specific heat budget. Our results caution that the metamorphic conditions derived from pelitic granulites should not be assumed or extrapolated to larger sections of an orogenic crust that consist of other, more refractory lithologies. |
