High-magnesium staurolite in a sapphirine-garnet rock from the Limpopo Belt,Southern Africa

Unusually Mg-rich staurolite with F=Fe/(Fe+ Mg) = 0.51 occurs in a peraluminous silica-deficient sapphirine-garnet-gedrite-spinel-corundum-phlogopite rock as relic inclusions within pyrope-almandine garnet (F=0.43–0.48), from which it is generally separated by sapphirine (F=0.19). Gedrite has F=0.24–0.27, phlogopite 0.19, and spinel 0.43. The gradual disappearance of staurolite is due to a shift of the 3-phase AFM assemblage staurolite-garnetsapphirine to more Fe-rich compositions according to probably prograde reactions between staurolite and garnet to form sapphirine together with either quartz or gedrite. Thus still more Mg-rich staurolite seems to have existed in the rock at earlier stages of metamorphism characterized by lower temperatures and perhaps higher pressures. The local equilibria now frozen in indicate minimum pressures of 7–8 kbar and temperatures in excess of about 800° C.Staurolite is free from Zn, very low in Si, and richer in Ti than any other staurolite found thus far. Most notable is the unique Mg/Fe fraction between staurolite and garnet with staurolite being the more Fe-rich phase (K_D=1.32).