A model of temporal variations in ozone density in the Martian atmosphere

Temporal variations of the Martian ozone density profile at high latitudes have been calculated for an entire Martian year, taking into account the seasonal and diurnal variations in temperature, water vapor and solar radiation. A new technique facilitates the long-term model calculations, including diurnal variations. The result is in better agreement with MARINER 9 observations of the time and magnitude of the seasonal maximum than is the result of the previous seasonal model calculated for the diurnally averaged temperature, water vapor and solar radiation. The large scatter of the MARINER 9 data may be partly experimental, but the effect of surface condition, including the water vapor variability and the surface chemistry, may explain some of the dispersion of the observed data. The predicted diurnal variation is substantial except near solstices, and the nighttime total column density is generally larger than the daytime value. The magnitude of the day-and-night difference and the shape of the diurnal variation change markedly with season. The opposite temporal variation is predicted for ozone density between the upper and lower regions. The model predicts the production of a ozone layer at 35–50 km, which is consistent with observations at low latitudes by MARS-5. The observed ozone density may be explained, if the atmospheric temperature is as low as ～ 140 K or if the atmosphere is subsaturated. Effects of the simultaneous existence of an aerosol layer, also observed by MARS-5, are briefly discussed.