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57Fe and 119Sn Mössbauer studies of natural tin-bearing garnets
Authors:G Amthauer  J R McIver  E A Viljoen
Institution:1. Institut für Mineralogie der Phillipps-Universit?t, Lahnberg, 3550, Marburg (Lahn), Germany
2. Department of Geology, University of the Witwatersrand, Milner Park, Johannesburg, South Africa
3. National Institute for Metallurgy, 200 Hans Strydom Avenue, Randburg, Johannesburg, South Africa
Abstract:The Mössbauer spectra of 119Sn and 57Fe in three natural and a synthetic garnet were studied between 20 and 300 K. These spectra reveal the presence of octahedral Sn4+ as well as octahedral Fe3+ and Fe2+. Sn2+ could not be detected. On the basis of these results the following cation substitution can be derived for the tin-bearing Silicate garnets of this study: Sn4+ (oct)+Fe2+ (oct) ? 2 Fe3+ (oct).
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