Ionic conductivity in sodium magnesium silicates |
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| Authors: | R D Shannon |
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| Institution: | 1. Central Research and Development Department, E.I. du Pont de Nemours and Company, Experimental Station, 19898, Wilmington, Delaware, U.S.A.
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| Abstract: | Na2MgSiO4 crystals prepared hydrothermally at 700° C and 3,000 atm are related to carnegieite with SG Pmn21, a=7.015(2), b=10.968(2), and c=5.260(1). Na conductivity in Na2MgSiO4 is 3.0×10?5 (ohm-cm)?1 at 300° C but can be raised to 1.1×10?3 (ohm-cm)?1 by creating Na vacancies in the composition Na1.9Mg0.9Al0.1O4. Na4Mg2Si3O10 is also a cristobalite-related carnegieite with the orthorhombic cell a=10.584(7), b=14.328(7), and c=5.233(5). The Na conductivity of Na4Mg2Si3O10 is 4.8×10?3 (ohm-cm)?1 at 300° C. |
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