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InterPreting effects of TOCinert organic content on source rock Potential using S2 vs. TOC graPh in Maamba Coalfield,southern Zambia
Authors:Cryton Phiri  WANG Pujun  G Roland Nguimbi  Abdallah-Yousif Ibrahim Hassan
Affiliation:1. College of Earth Sciences,Jilin University,Changchun 130061,China; 2. Geology Department,University of Zambia,Lusaka 10101,Zambia; 3. College of Construction Engineering,Jilin University,Changchun 130026,China
Abstract:The authors present the effects of the total organic carbon (TOC inert ) during pyrolysis and how it overall affects the estimates of the hydrocarbon index (HI) using the cross plot S 2 vs. TOC graph. A total of 21 drillcore samples consisting of the non- carbonaceous mudstones,carbonaceous mudstones,coaly mudstones and coals with S 2 > 0. 35 are selected and used. The average TOC for the sampled population is 10. 36 wt%. TOC inert measured from the S 2 vs. TOC graph is 2. 97 wt% and the average pyrolysable TOC live is 7. 39 wt%. The HI is 102 mg HC/g TOC and the pyrolysable HI is 175 mg HC/g TOC,indicating that the TOC inert or mi- neral matrix adsorbs some of the hydrocarbons liberated during pyrolysis resulting into the low HI values which affects the correct determination of the source rock potential. Other applications of the S 2 vs. TOC cross plot have been used to determine the depositional system tracts. The high stand system tract is also determined through this method.
Keywords:Rock-Eval Pyrolysis  S2 vs. TOC  Maamba Coalfield Basin  Zambia
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