Abstract: | Despite the association of certain characteristic trace-element signatures with particular tectonic environments of eruption, there are accumulating data which would result in significant tectonic misassignments. Ambiguity of signals appears in active arc/back-arc systems of the southwestern Pacific and particularly in some intracontinental plate suites. Given the selective preservation of continental as opposed to oceanic lithosphere, inappropriate paleotectonic inferences are probable using trace-element criteria alone.Strong relative fractionation of the alkalis and alkaline earth elements (AEE) with respect to the rare earth elements (REE) in the majority of arc-related magmas and a number of intraplate continental basalts is strongly suggestive of the involvement of hydrous fluids at some stages in the respective petrogenetic processes occurring in these two tectonic regimes. In contrast, fractionation of high-field-strength elements (HFSE) such as Nb and Ta with respect to the REE in the same suites is most readily explained by the involvement, at some stage in the magma formation process, of high-SiO2 melts. A number of widely applied tectonic discriminants makes use of AEE/HFSE fractionation, but the processes and sources involved in subduction-zone petrogenesis may be duplicated during interaction of mantle-derived basalt with the heterogeneous components of continental lithosphere, both mantle and crust. A significant role for both volatile-dominated fluids and silicate melts is implicated in collision and some intracontinental plate magmatism. |