Heat capacity,compressibility and thermal expansion coefficient of ilmenite-type MgGeO3

The accuracy of differential scanning calorimetry (DSC) on a heat capacity measurement was evaluated using MgO. The result indicated that the deviation of the result in comparison to literature values was less than 0.4% at temperatures above 300 K and 2.1% below this temperature. Since this experiment proved the reliability of DSC, heat capacity, compressibility, and thermal expansion of ilmenite-type MgGeO₃ were measured by means of DSC, a diamond anvil high pressure device, and a high-temperature X-ray camera, respectively. The heat capacity was approximated by C _p = a + b·T + c·T ^?2 at high temperatures and by the Debye function at low temperatures. The compressibility was well-represented by the Murnaghan-Birch equation of 2nd order. The thermal expansion coefficient was constant up to 1073 K.