华北地区京西煤田侏罗纪煤层中伊利石矿物学特征及成因

为了探讨伊利石对煤化作用和沉积环境的指示作用,以华北地区京西煤田侏罗纪煤层夹矸为研究对象,采用X射线衍射方法(XRD)和X射线荧光方法(XRF)分别测定煤层夹矸的矿物组成和化学组成,研究夹矸中伊利石矿物学特征及成因。结果表明,京西煤田侏罗纪煤层夹矸主要由伊利石、绿泥石和石英组成,其中,伊利石质量分数平均为62.92%。将XRD数据和XRF数据进行对比分析,计算得到伊利石平均化学式为(K0.37(NH4)0.03)Al2(Si3.60Al0.40O10)(OH)2。京西煤田煤层夹矸中伊利石主要由高岭石转化而来,伊利石的NH4+占层间阳离子的比例具有随沉积古盐度升高而逐渐升高的趋势,n(Si)/n(Al)Ⅳ具有随煤化程度升高而逐渐降低的趋势,这表明京西煤田侏罗纪煤层夹矸中的伊利石矿物学特征对沉积环境和煤化作用具有一定的指示作用。

Mineralogical characteristics and genesis of the illite in Jurassic coal of the Jingxi coalfield,North China

In order to study the indicating effect of illite for coalification and sedimentary environments, the Jurassic coal seam gangue in Jingxi coalfield of North China was taken as the research object. X-ray diffraction(XRD) and X-ray fluorescence(XRF) were used to determine the mineral composition and chemical composition of the gangue sandwiched in the coal seam gangue. The mineralogical characteristics and genesis of illite in the gangue were studied. The results indicated that the intra-seam partings are mainly composed of illite, chlorite and quartz, followed by small amount of calcite and albite. The illite has an average proportion of 62.92%. According to the comparison of XRD data and XRF data, the average chemical formula of the illite can be calculated as (K_0.37(NH₄)_0.03)Al₂(Si_3.60Al_0.40O₁₀)(OH)₂. The illite in the intra-seam partings of Jurassic coal of the Jingxi coalfield is mainly converted from kaolinite, and the NH₄+ proportion of the illite has an increasing trend with the increase of depositional paleosalinity, and the n(Si)/n(Al)Ⅳ of the illite has a decreasing trend along with coalification. This indicates that the mineralogical characteristics of the illite in the intra-seam partings can be used as indicators of coalification and depositional environment.