Geochemistry of the early proterozoic metasedimentary rocks of the alligator rivers region,Northern Territory,Australia

The early Proterozoic metasedimentary sequence of the Alligator Rivers Region (a part of the Pine Creek Geosyncline) in the Northern Territory, Australia, overlies an Archaean granitoid basement. Early Proterozoic sedimentary sequences, in general, record important changes in the composition of the upper continental crust about the Archaean-Proterozoic boundary. However, the geochemistry of only a few of these sequences has been documented. The geochemistry of the early Proterozoic succession in the Alligator Rivers Region is reported here and the results are interpreted in terms of differences between the stratigraphic units, their provenance—particularly in relation to crustal evolution, and their subsequent metamorphism and weathering.Clastic metasedimentary rocks throughout the Alligator Rivers Region have a remarkably uniform major and trace element geochemistry. The Kakadu Group and upper member of the Cahill Formation are relatively more enriched in SiO₂ and correspondingly more depleted in Al₂O₃ than the rest of the sequence, reflecting the greater dominance of metapsammitic assemblages. The lower member of the Cahill Formation, which hosts the major U deposits of the Alligator Rivers Region, and the metasedimentary sequence in general, exhibit no significant enrichment in U above normal background values. Rare earth element (REE) concentrations in the metasedimentary units within the Alligator Rivers Region are uniform, though in detail there are some important differences within and between formations.The composition of the early Proterozoic clastic metasediments in the Alligator Rivers Region is consistent with the composition of similar material of the same age from other areas, and supports current ideas on crustal evolution. The Alligator Rivers metasediments are enriched in Si and K, and depleted in Mg, Ca, and Na relative to the Archaean average for clastic sedimentary rocks, and their REE geochemistry resembles typical post-Archaean sedimentary rocks having a light REE enriched pattern and a distinct Eu/Eu1 depletion compared to typical Archaean sediments. However, the REE data indicate that two compositionally distinct sources are involved in the provenance of the Kakadu Group, and possibly the lower member of the Cahill Formation, where two types of REE patterns can be distinguished on their HREE concentration and Eu/Eu1 anomaly.