Structure and composition of the continental crust in East China

Crustal structures of nine broad tectonic units in China, except the Tarim craton, are derived from 18 seismic refraction profiles including 12 geoscience transects. Abundances of 63 major, trace and rare earth elements in the upper crust in East China are estimated. The estimates are based on sampling of 11 451 individual rock samples over an area of 950 000 km², from which 905 large composite samples are prepared and analyzed by 13 methods. The middle, lower and total crust compositions of East China are also estimated from studies of exposed crustal cross sections and granulite xenoliths and by correlation of seismic data with lithologies. All the tectonic units except the Tarim craton and the Qinling orogen show a four-layered crustal structure, consisting of the upper, middle, upper lower, and lowermost crusts. P-wave velocities of the bulk lower crust and total crust are 6.8–7.0 and 6_:4–6.5 km/s, respectively. They are slower by 0.2–0.4 km/s than the global averages. The bulk lower crust is suggested to be intermediate with 58% SiO₂ in East China. The results contrast with generally accepted global models of mafic lower crusi. The proposed total crust composition in East China is also more evolved than previous estimates and characterized by SiO₂=64%, a significant negative Eu anomaly (Eu/Eu* = 0.80), deficits in Sr and transition metals, a near-arc magma La/Nd ratio (3.0), and a calculatedμ(²³⁸U/²⁰⁴Pb) value of 5. In addition, it has the following ratios of element pairs exhibiting similar compatibility, which are identical or close to the primitive mantle values: Zr/Hf=37, Nb/Ta=17.5, Ba/Th=87, K/Pb=0.12x10⁴, Rb/Cs=25, Ba/Rb=8.94, Sn/Sm=0.31, Se/Cd=1.64, La/ As=10.3, Ce/Sb=271, Pb/Bi=57, Rb/TI=177, Er/Ag=52, Cu/Au=3.2×10⁴, Sm/Mo=7.5, Nd/W=40, CI/Li=10.8, F/Nd=21.9, and La/B=1.8. Project supported by the National Natural Science Foundation of China (Grant Nos. 49625305, 49573183, 49673184, 49794043), the State Comission of Education, the Ministry of Geology and Mineral Resources of China (Grant No. 850514), the Open Laboratory of Constitution, Interaction and Dynamics of the Crust-Mantle System, and the Alexander-von-Humboldt Foundation of Germany.