Structural identification of the C25 highly branched isoprenoid pentaene in the marine diatom Rhizosolenia setigera |
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| Authors: | Jaap S. Sinninghe Damst , Stefan Schouten, W. Irene C. Rijpstra, Ellen C. Hopmans, Harry Peletier, Winfried W. C. Gieskes,Jan A. J. Geenevasen |
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| Affiliation: | a Netherlands Institute for Sea Research (NIOZ), Department of Marine Biogeochemistry and Toxicology, PO Box 59, 1790 AB Den Burg, Texel, The Netherlands;b Department of Marine Biology, University of Groningen, PO Box 14, 9750 AA Haren, The Netherlands;c University of Amsterdam, Faculty of Chemistry, Department of Organic Chemistry, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands |
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| Abstract: | 2,6,10,14-tetramethyl-7-(3-methylpent-4-enyl)-pentadeca-2,5E,9E,13-tetraene I possessing a C25 highly branched isoprenoid skeleton has been isolated from the marine diatom Rhizosolenia setigera and identified by 1H and 13C NMR spectroscopy. |
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| Keywords: | Highly branched isoprenoid alkenes NMR spectroscopy Rhizosolenia setigera |
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