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Oxygen isotope and fluid inclusion study of the Sorkhe-Dizaj iron oxide-apatite deposit,NW Iran
Abstract:The Sorkhe-Dizaj orebody is located 32 km southeast of Zanjan within the Tarom subzone of the Alborz-Azarbaijan structural zone. It is hosted mainly in quartz monzonite-monzodiorite and, to a lesser extent, in volcanoclastic rocks. Mineralization occurs in the form of stockwork and veins, comprising predominantly magnetite and actinolite, with minor pyrite and chalcopyrite. Two generations of magnetite and apatite are inferred: the first as disseminations in the host rock and the second mainly as an alteration product of actinolite, secondary K-feldspar, silica, sericite, chlorite and epidote. Fluid inclusion studies were carried out on second-generation apatite, and late-stage quartz to understand the geochemical evolution of the ore-bearing fluids. Fluid inclusions are of three types, i.e. primary, secondary, and pseudo-secondary. These inclusions are liquid or vapour single-phase, two-phase rich in liquid or vapour, and three-phase. Homogenization temperatures of second-generation apatite are inferred to be between 209°C and 520°C (mostly between 290°C and 320°C), indicating salinities of 9.08–21.61 wt.% NaCl equiv. At 342°C, the δ18O values range from 9‰ to 11.32‰ for the second-generation magnetite associated with coeval apatite. Fluid inclusions in the late-stage quartz veins are inferred to have homogenized between 186°C and 263°C, with δ18O values ranging between 2.5‰ and 7.4‰ at 220°C. Oxygen isotopes in the late-stage carbonate veins have values of 3.28–6.14‰ at 100°C. These data in the late-stage veins imply introduction of a cooler, less saline, isotopically depleted fluid, probably meteoric water. Field observations, mineral parageneses, and fluid inclusion?+?oxygen isotope data suggest that the magnetite-apatite veins formed from a predominantly magmatic-derived fluid. Introduction of cooler meteoric water in the final stage of mineralization reduced δ18O values, facilitating precipitation of sulphides, quartz, and carbonate veins.
Keywords:Alborz-Azarbaijan structural zone  magnetite-apatite orebody  Sorkhe-Dizaj deposit  Zanjan  Iran
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