Zincian dolomite from broken hill,New South Wales

Many Broken Hill (New South Wales) specimens labelled ‘zinco‐calcite’ in museum and private collections are snow‐white, globular forms with a sparkling appearance, on a coronadite or limonite matrix. X‐ray diffraction and microprobe analyses show the globules have a core of nearly pure calcite, overlain by colourless, drusy zincian dolomite with up to 4 mol % ZnCO₃ and up to 7 mol % excess CaCO₃. Although Zn is abundant in the Broken Hill orebody, it apparently entered carbonate, mainly as smithsonite, only during formation of the oxidised zone.