Carbon isotopes in the rivers from the Lesser Antilles: origin of the carbonic acid consumed by weathering reactions in the Lesser Antilles

In this paper, we use carbon isotopes in the dissolved load of rivers from the Lesser Antilles volcanic arc (Guadeloupe, Martinique and Dominica islands) to constrain the source of the carbon dioxide (CO₂) involved in the neutralization reactions during water–rock interactions. The δ¹³C data span a large range of variations, from –19‰ to –5 · 2‰ for DIC (dissolved inorganic carbon) concentrations ranging from 11 μM to 2000 μM. Coupled with major element concentrations, carbon isotopic ratios are interpreted as reflecting a mixture of magmatic CO₂ (enriched in heavy carbon (δ¹³C ≈ –3 · 5‰) and biogenic CO₂ produced in soils (enriched in light carbon (δ¹³C < –17‰)). Carbon isotopes show that, at the regional scale, 23 to 40% of CO₂ consumed by weathering reactions is of magmatic origin and is transferred to the river system through aquifers under various thermal regimes. These numbers remain first‐order estimates as the major uncertainty in using carbon isotopes as a source tracer is that carbon isotopes can be fractionated by a number of processes, including soil and river degassing. Chemical weathering is clearly, at least, partly controlled by the input of magmatic CO₂, either under hydrothermal (hot) or surficial (cold) weathering regimes. This study shows that the contribution of magmatic CO₂ to chemical weathering is an additional parameter that could explain the high weathering rates of volcanic rocks. The study also shows that a significant part of the carbon degassed from the Earth's interior is not released as CO₂ to the atmosphere, but as DIC to the ocean because it interacts with the groundwater system. This study calls for a better understanding of the contributions of deep carbon to the hydrosphere and its influence on the development of the Critical Zone. Copyright © 2013 John Wiley & Sons, Ltd.