Electron microscopic examination of hydrothermally treated bentonite clay

Water-saturated Na bentonite clay with a bulk density of 2 g/cm³ was autoclaved at 150 and 200°C for up to 0.5 years and then left to rest under confined conditions at room temperature for several weeks. Transmission electron microscopy with elemental micro-analysis was applied to study hydrothermally induced changes, which were found to have the form of particle reorganization and, at 200°C, release and precipitation of silica. The precipitations are suspected to be hydrated amorphous silica gels. The microstructural alteration, which was more obvious at 200°C than at 150°C, involved regrouping of previously dispersed and expanded stacks of montmorillonite flakes to yield dense branches of interwoven, contracted stacks separated by large voids.