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L'archivage des activités humaines par les neiges et glaces polaires : le cas du plomb
Authors:Claude Boutron  Kevin Rosman  Carlo Barbante  Michael Bolshov  Freddy Adams  Sungmin Hong  Christophe Ferrari
Affiliation:1. Laboratoire de glaciologie et géophysique de l''environnement, UMR CNRS 5183, 54, rue Molière, domaine universitaire, BP 96, 38402 Saint-Martin-d''Hères cedex, France;2. UFR de physique et Observatoire des sciences de l''Univers, université Joseph-Fourier, domaine universitaire, BP 68, 38041 Grenoble cedex, France;3. Institut universitaire de France, Maison des Universités, 103, bd Saint-Michel, 75005 Paris, France;4. Department of Applied Physics, Curtin University of Technology, GPO Box U 1987, Perth, Western Australia 6845, Australie;5. Department of Environmental Sciences, University of Venice, Ca''Foscari, Calle Larga Santa Marta 2137, 30123 Venice, Italie;6. Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Calle Larga Santa Marta 2137, 30123 Venice, Italie;7. Institute of Spectroscopy, Russia Academy of Sciences, Troitzk, 142092 Moscow Region, Russie;8. Micro and Trace Analysis Center, Department of Chemistry, University of Antwerpen (UIA), Universiteitsplein 1, 2610 Wilrijk, Belgique;9. Polar Sciences Laboratory, Korea Ocean Research and Development Institute, Ansan, P.O. Box 29, 425–600 Seoul, République de Corée;10. Polytech Grenoble, université Joseph-Fourier, 28, av. Beno??t-Frachon, BP 53, 38041 Grenoble, France
Abstract:The investigation of the occurrence of lead in dated snow and ice from Greenland and Antarctica has played a major role in our understanding of the history of the pollution of the atmosphere of our planet by this metal. Such studies have however proved to be very demanding, mainly because of the extreme purity of polar snow and ice. Reliable measurements can be obtained only if ultra-clean and highly sensitive procedures are used, as pioneered by Clair Patterson. The Greenland data show evidence of large-scale pollution of the atmosphere of the Northern Hemisphere for lead as early as two millennia ago during Greco–Roman times, especially because of mining and smelting activities in southern Spain. It peaked at the end of the 1960s, with lead concentrations in snow about 200 times higher than natural values, before declining during recent times because of the fall in the use of leaded gasoline. Lead pollution in Antarctica was already significant at the end of the 19th century as a consequence of whaling activities, the traffic of coal-powered ships crossing the Cape Horn, and mining activities in South America, South Africa and Australia. After declining because of the opening of the Panama Canal, the great economic depression and World War II, it reached a maximum during the 1980s, with lead concentrations 20 times higher than natural values. Other studies focus on past natural variations of lead in ancient ice dated from the last climatic cycles. To cite this article: C. Boutron et al., C. R. Geoscience 336 (2004).
Keywords:plomb  neige  glace  ultratraces  isotopes  spéciation  pollution  Empire romain  essence plombée  lead  snow  ice  trace analysis  isotopes  speciation  pollution  Roman Empire  leaded gasoline
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