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纳米金的迁移富集与黄铁矿富金关系
引用本文:姜泽春,章振根.纳米金的迁移富集与黄铁矿富金关系[J].矿产与地质,1998,12(6):367-371.
作者姓名:姜泽春  章振根
作者单位:中国科学院贵阳地球化学研究所
摘    要:黄铁矿是金矿床中常见的矿物,也是重要的载金矿物之一,有的黄铁矿富金,有的黄铁矿不含金或含微量金。为什么黄铁矿对纳米金的吸附作用强?讨论了纳米微粒金与黄铁矿的关系后指出,半导体型黄铁矿有N型和P型两种。前者具负热电动势、带负电;后者具正电位带正电荷。当其与SiO2水溶液迁移时,若与带正电荷的P型黄铁矿相遇,即被P型黄铁矿吸附沉淀成矿。带负电荷的黄铁矿不能吸附带负电荷的纳米金,因而不能成矿。

关 键 词:纳米金,半导体型黄铁矿,自然电场,氧化还原环境,金的地球化学

TRANSPORT AND ENRICHMENT OF NANOMETER SIZED GOLD IN RELATION TO GOLD RICH PYRITE
Jiang Zechun,Zhnag Zhengen,Mo Deming,Chen Damei.TRANSPORT AND ENRICHMENT OF NANOMETER SIZED GOLD IN RELATION TO GOLD RICH PYRITE[J].Mineral Resources and Geology,1998,12(6):367-371.
Authors:Jiang Zechun  Zhnag Zhengen  Mo Deming  Chen Damei
Abstract:Pyrite is a common mineral in gold ore deposits and one of the important gold rich minerals.Some pyrites are rich in gold and other contain no or a trace amount of gold.Why does pyrite have such a strong capacity of adsorbing nanometer sized gold? The paper discusses the relation between nanometer sized gold and pyrite,it points out that there are two types of semiconductive pyrite:N pyrite and P pyrite.The former with negative charge is possessed of negative thermoelectromotive force;the latter with positive charge is possessed of the positive thermoelectromotive force.When nanometer sized gold is transported with aqueous solution of silicondioxide and encountered with P pyrite,it will be adsorbed on pyrite,followed by ore deposition.N pyrite with negative charge can not adsorbnanometer sized gold with negative charge,and therefore no gold deposition would occur.
Keywords:Nanometer  sized gold  Semiconductive type of pyrite  Gold geochemistry  Redox environment  Natural electric field
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