Laser argon-40-argon-39 age determinations of Luna 24 mare basalts

Abstract— The ages of seven rock fragments from the soil fraction of the Luna 24 core have been determined using a laser ⁴⁰Ar-³⁹Ar stepped heating technique. The investigated lithologies include fragments of fine-grained ophitic basalt, coarse-grained basalt, metabasalts and a regolith breccia. Most of the samples contain nonradiogenic Ar components of variable ³⁶Ar/⁴⁰Ar composition. These surface-correlated trapped components are predominantly released at low temperature and can be distinguished from volume-correlated radiogenic and cosmogenic components released at higher temperature during stepped heating. Binary mixtures of radiogenic and cosmogenic Ar components give linear correlations on ³⁶Ar_t/⁴⁰Ar-³⁹Ar/⁴⁰Ar diagrams from which the age and ³⁶Ar/⁴⁰Ar value of trapped Ar can be determined. The ages obtained span a narrow range between 3.18-3.28 Ga with an average of 3.22 ± 0.04 Ga. This is interpreted as being the age of the basalts at the Luna 24 sampling site. Systematic age differences between lithologies were not detected; however, a single age of 2.93 Ga obtained from a coarse-grained basalt hints at the possibility of younger volcanism. The results of this work effectively triple the chronological information available for Mare Crisium and are within the range of radiometric age measurements of Luna 24 mare basalts obtained previously.