Scattering of light from particulate surfaces: I. A laboratory assessment of multiple-scattering effects

A convenient photometric function for many particulate surfaces is the generalization of the Lommel-Seeliger law derived by Hapke (1963) and Irvine (1966). This generalization accounts for the effects of mutual shadowing among particles, but still assumes that multiple scattering within the surface layer can be neglected—an assumption which is evidently valid for dark surfaces. We describe a series of laboratory measurements which test the range of validity of this basic assumption, and the applicability of the Hapke-Irvine photometric function, for particulate surfaces whose normal reflectances ranges from 0.04 to 1.04. We find that multiple-scattering effects can be neglected, and that the Hapke-Irvine function can be used, for particulate surfaces whose normal reflectance is about 0.3, or less. The function is definitely inapplicable to surfaces whose normal reflectance exceeds 0.4.