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石油污染多孔介质湿润性变异特征
引用本文:梁春,郑西来,张俊杰. 石油污染多孔介质湿润性变异特征[J]. 地球科学, 2011, 36(4): 765-770. DOI: 10.3799/dqkx.2011.078
作者姓名:梁春  郑西来  张俊杰
作者单位:中国海洋大学海洋环境与生态教育部重点实验室,山东青岛 266100
基金项目:国家自然科学基金项目(No.40872150)
摘    要:一定程度的石油污染可使多孔介质的湿润性发生变异,导致介质持水能力降低、地下水石油污染、粮食产量品质下降等.采用滴水穿透时间法与酒精溶液入渗法,测定了亚粘土和粗砂在不同柴油、机油含量下的斥水水平,确定了亚粘土、粗砂由亲水表面变为疏水表面的临界含油量.结果表明,亚粘土、粗砂湿润性变异的临界机油含量分别约为7%、0.5%,粗砂湿润性变异的临界柴油含量约为14%,而柴油污染对亚粘土湿润性的影响不显著.另外,当石油污染多孔介质的含水量达到某一临界值时,湿润性将再次发生反转,由疏水表面变回亲水表面.测得机油、柴油污染粗砂的临界含水量约在0.2%~1%之间,机油污染亚粘土的临界含水量在数值上与其含油量近似相等. 

关 键 词:石油污染多孔介质   湿润性   斥水性   污染控制   环境工程
收稿时间:2010-11-09

Characteristics of Wettability Variation of Oil-Contaminated Porous Medium
LIANG Chun,ZHENG Xi-lai,ZHANG Jun-jieKey Laboratory of Ocean Environment , Ecology,Ministry of Education,Ocean University of China,Qingdao ,China. Characteristics of Wettability Variation of Oil-Contaminated Porous Medium[J]. Earth Science-Journal of China University of Geosciences, 2011, 36(4): 765-770. DOI: 10.3799/dqkx.2011.078
Authors:LIANG Chun  ZHENG Xi-lai  ZHANG Jun-jieKey Laboratory of Ocean Environment    Ecology  Ministry of Education  Ocean University of China  Qingdao   China
Affiliation:LIANG Chun,ZHENG Xi-lai,ZHANG Jun-jieKey Laboratory of Ocean Environment and Ecology,Ministry of Education,Ocean University of China,Qingdao 266100,China
Abstract:A certain degree of oil pollution can lead to wettability variation in porous medium,which can bring about low water-holding capacity,oil contamination of groundwater,low food quality and production.In this study,water repellency of sand and clay was measured by WDPT and MED methods under different diesel and engine oil contents.Critical oil content of porous media in oil-contaminated porous media was determined preliminarily,beyond which hydrophilic surface could change into hydrophobic surface.The results...
Keywords:oil-contaminated porous medium  wettability  water repellency  pollution control  environmetal engineering.  
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