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表面活性剂强化空气扰动修复氯苯污染含水层
引用本文:秦传玉,赵勇胜,郑苇. 表面活性剂强化空气扰动修复氯苯污染含水层[J]. 地球科学, 2011, 36(4): 761-764. DOI: 10.3799/dqkx.2011.077
作者姓名:秦传玉  赵勇胜  郑苇
作者单位:1.长春理工大学化学与环境工程学院,吉林长春 130022
基金项目:国家高技术研究发展“863”计划项目(No.2008AA06A410)
摘    要:
通过一维砂柱实验研究了阴离子表面活性剂十二烷基苯磺酸钠(SDBS)对空气扰动技术(air sparging,AS)修复氯苯污染地下水的强化效果.结果表明,SDBS的加入降低了地下水的表面张力,减小了水气两相毛细压力,从而提高了地下水中的空气饱和度.当曝气量为100 mL/min,地下水的表面张力由72.2 mN/m降至49.5 mN/m时,地下水中空气饱和度由13.2%提高至50.1%,而后随着表面张力的进一步降低,空气饱和度不再提高,反而有小幅下降.通过污染物的去除实验发现,SDBS的加入大大提高了氯苯的去除率,且去除率的变化与空气饱和度的变化趋势基本相符.因此,表面活性剂的加入可以作为空气扰动技术一种十分有效的强化手段. 

关 键 词:表面活性剂强化   空气扰动   污染控制   空气饱和度   环境工程
收稿时间:2010-10-15

Remediation of Chlorobenzene Polluted Aquifer by Surfactant-Enhanced Air Sparging
QIN Chuan-yu,ZHAO Yong-sheng,ZHENG Wei.School of Chemistry , Environmental Engineering,Changchun University of Science , Technology,Changchun ,China.College of Environment , Resources,Jilin University,Changchun ,China. Remediation of Chlorobenzene Polluted Aquifer by Surfactant-Enhanced Air Sparging[J]. Earth Science-Journal of China University of Geosciences, 2011, 36(4): 761-764. DOI: 10.3799/dqkx.2011.077
Authors:QIN Chuan-yu  ZHAO Yong-sheng  ZHENG Wei.School of Chemistry    Environmental Engineering  Changchun University of Science    Technology  Changchun   China.College of Environment    Resources  Jilin University  Changchun   China
Affiliation:QIN Chuan-yu1,ZHAO Yong-sheng2,ZHENG Wei21.School of Chemistry and Environmental Engineering,Changchun University of Science and Technology,Changchun 130022,China2.College of Environment and Resources,Jilin University,Changchun 130026,China
Abstract:
The strengthening effect of anionic surfactant sodium dodecyl benzene sulfonate(SDBS) on air sparging(AS) was investigated using a series of one-dimensional column experiments.The results show that the addition of SDBS into groundwater lowered the groundwater surface tension,which in turn reduced the air entry capillary pressure.As a result,the air saturation in groundwater was increased accordingly.At the air injection rate of 100 mL/min,the surface tension reduction from 72.2 mN/m to 49.5 mN/m led to air ...
Keywords:surfactant-enhanced  air sparging  pollution control  air saturation  environmental engineering.  
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