Optimized NMR spectroscopic strategy to characterize water dynamics in soil samples

¹H wideline NMR spectra of soil samples offer the possibility to analyze soil material based on their proton mobility. Care has to be taken to remove unwanted signal contributions from the probe background. We demonstrate that unstructured wideline spectra can be analyzed quantitatively by a combination of a Gaussian line for rigid and a Lorentzian line for mobile protons. This is used to study effects of hydrogen-bonded water networks upon heat treatment for a series of different soil samples with varying water content as a contribution to study physical aging of soil organic matter (SOM). Results are combined with ¹H projections from ¹³C 2D WISE (wideline separation) experiments representing solely the broad Gaussian line. Furthermore, for the first time applied to soils, ¹H structural information from soil samples is obtained from 2D PMLG phase modulated Lee-Goldburg measurements under magic angle spinning (MAS). Low water contents improve the resolution of main functional groups significantly.