Physicomechanical properties of cryptocrystalline fluorite from the Suran deposit, southern Urals

Microhardness (H) and fracture toughness (K _1C) have been studied for the main varieties of shock-resistant cryptocrystalline fluorite, a natural ceramic widespread at the Suran deposit. Suran cryptocrystalline fluorite (SCF) is characterized by high fracture toughness (K _1C), which is 2–5 times higher than K _1C of common fluorite monocrystals. The relationship between K _1C and microhardness H is complex and nonlinear. The SCF varieties from the sellaite-fluorite orebody are distinguished by the highest K _1C = 1.9–2.3 MPa m^1/2, which exceeds K _1C = 0.84 MPa m^1/2 of porcelain-like fluorite from the main fluorite orebody. Qualitative and quantitative variations of structural point defects in the studied samples exert a much stronger effect on microhardness than on fracture toughness, which mainly depends on the size of crystallites, their mutual crystallographic orientation, and the structure of intergranular boundaries, i.e., on the parameters seemingly related to recrystallization and/or twinning of fluorite. In general, the nature of the Suran deposit of fluorite ceramic with unusual physicomechanical properties remains a geological puzzle in many respects.