A Raman spectroscopic study of shock-wave densification of anorthite (CaAl2Si2O8) glass |
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Authors: | B Reynard M Okuno Y Shimada Y Syono C Willaime |
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Institution: | (1) Géosciences Rennes CNRS UPR 4661, Université de Rennes1, F. 35042 Rennes Cedex, France E-mail: breynard@ens-lyon.fr, FR;(2) Department of Earth Sciences, Faculty of Science, Kanazawa University, Kanazawa, 920-1192, Japan, JP;(3) Institute for Material Research, Tohoku University, Sendai, 980, Japan, JP |
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Abstract: | Structural modifications induced by shock-wave compression up to 40 GPa in anorthite glass are investigated by Raman spectroscopy.
In the first investigation, densification increases with increasing shock pressure. A maximum densification of 2.2% is obtained
for a shock pressure of 24 GPa. This densification is attributed to a decrease of the average ring size, favoring three-membered
rings. The densification is much lower than in silica glass subject to shock at similar pressures (11%), because the T-O-T
bond angle decrease is impeded in anorthite glass. For higher shock pressures, the decrease of the recovered densification
is attributed to partial annealing of the samples due to high after-shock residual temperatures. The study of the annealing
process of the most densified glass by in-situ high temperature Raman spectroscopy confirms that relaxation of the three-membered
rings occurs above about 900 K.
Received: 21 July 1998 / Revised and accepted: 27 January 1999 |
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Keywords: | anorthite glass shock compression densified glass Raman spectroscopy |
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