首页 | 本学科首页   官方微博 | 高级检索  
     检索      


A Raman spectroscopic study of shock-wave densification of anorthite (CaAl2Si2O8) glass
Authors:B Reynard  M Okuno  Y Shimada  Y Syono  C Willaime
Institution:(1) Géosciences Rennes CNRS UPR 4661, Université de Rennes1, F. 35042 Rennes Cedex, France E-mail: breynard@ens-lyon.fr, FR;(2) Department of Earth Sciences, Faculty of Science, Kanazawa University, Kanazawa, 920-1192, Japan, JP;(3) Institute for Material Research, Tohoku University, Sendai, 980, Japan, JP
Abstract:Structural modifications induced by shock-wave compression up to 40 GPa in anorthite glass are investigated by Raman spectroscopy. In the first investigation, densification increases with increasing shock pressure. A maximum densification of 2.2% is obtained for a shock pressure of 24 GPa. This densification is attributed to a decrease of the average ring size, favoring three-membered rings. The densification is much lower than in silica glass subject to shock at similar pressures (11%), because the T-O-T bond angle decrease is impeded in anorthite glass. For higher shock pressures, the decrease of the recovered densification is attributed to partial annealing of the samples due to high after-shock residual temperatures. The study of the annealing process of the most densified glass by in-situ high temperature Raman spectroscopy confirms that relaxation of the three-membered rings occurs above about 900 K. Received: 21 July 1998 / Revised and accepted: 27 January 1999
Keywords:anorthite glass  shock compression  densified glass  Raman spectroscopy
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号