Groundwater quality variations in glacial drift and bedrock aquifers,Barry County,Michigan, U.S.A.

Groundwater samples from 288 domestic wells in Barry County, Michigan, were analyzed for 33 inorganic chemical parameters. Variations in chemical composition were investigated by considering the possible effects of human impact, aquifer type (bedrock vs glacial drift), chemical evolution along groundwater flow paths, and glacial landform type (moraine vs outwash). Approximately 25 percent of the glacial drift wells were classified as degraded by human impact and were excluded from further analysis of chemical variation. Two-sample tests comparing individual concentrations from drift and bedrock aquifers suggest that groundwater in the Marshall Sandstone aquifer is derived from local recharge through the glacial drift. This conclusion is supported by generalized groundwater flow patterns recognized for the two aquifers.Concentrations in both aquifers were examined in relation to generalized flow paths derived from water level data and also by classification of wells as recharge, transition, and discharge. No spatial concentration trends in major ions were detected, although iron concentrations do appear to increase from recharge to discharge areas. Declining redox potential along groundwater flow paths may explain this trend.The possible influence of glacial landform type was investigated by comparing concentrations of wells in moraines with those in outwash deposits. Wells in moraines have significantly higher concentrations of most parameters, perhaps due to higher content of finer, more chemically reactive sediment grains.