Rapid migration of heavy metals and 137Cs in alluvial sediments,Upper Odra River valley,Poland

The studies presented explore post-depositional changes of zinc, cadmium, lead, manganese and ¹³⁷Cs distribution in alluvial sediments accumulated in the upper Odra River valley in southern Poland. The rate of these changes was estimated by comparing metal and ¹³⁷Cs distributions in four vertical alluvial profiles with a history of river pollution and sediment deposition. The untypical ¹³⁷Cs distribution with peaks in the surface 40–60 cm and lower down, even at a depth of 2.5 m in strata deposited before the beginning of nuclear tests in 1954, indicates rapid post-depositional migration of this isotope from the surface and its retention in lower, less permeable layers. Moreover, the highest concentrations of lead, zinc and cadmium were found at a depth of 4 m in sediments accumulated in the mid-nineteenth century in spite of the growth of industrialization and the pollution of the Odra River with heavy metals until the end of the twentieth century. The post-depositional changes in heavy metals and ¹³⁷Cs are rapid in comparison with the slow element migration usually observed in uninundated soils. This difference is explained by the frequent and easy infiltration of polluted river water into the gravelly and sandy sediments present in the profiles.