In situ radiometric dating on Mars: Investigation of the feasibility of K-Ar dating using flight-type mass and X-ray spectrometers

The absolute chronology of Mars is poorly known and, as a consequence, a key science aim is to perform accurate radiometric dating of martian geological materials. The scientific benefits of in situ radiometric dating are significant and arguably of most importance is the calibration of the martian cratering rate, similar to what has been achieved for the Moon, to reduce the large uncertainties on absolute boundary ages of martian epochs. The Beagle 2 Mars lander was capable of performing radiometric date measurements of rocks using the analyses from two instruments in its payload: (i) the X-ray Spectrometer (XRS) and (ii) the Gas Analysis Package (GAP). We have investigated the feasibility of in situ radiometric dating using the K-Ar technique employing flight-like versions of Beagle 2 instrumentation. The K-Ar ages of six terrestrial basalts were measured and compared to the ‘control’ Ar-Ar radiometric ages in the range 171-1141 Ma. The K content of each basalt was measured by the flight spare XRS and the ⁴⁰Ar content using a laboratory analogue of the GAP. The K-Ar ages of five basalts broadly agreed with their corresponding Ar-Ar ages. For one final basalt, the ⁴⁰Ar content was below the detection limit and so an age could not be derived. The precision of the K-Ar ages was ∼30% on average. The conclusions from this study are that careful attention must be paid to improving the analytical performance of the instruments, in particular the accuracy and detection limits. The accuracy of the K and Ar measurements are the biggest source of uncertainty in the derived K-Ar age. Having investigated the technique using flight-type planetary instrumentation, we conclude that come of the principle challenges of conducting accurate in situ radiometric dating on Mars using instruments of these types include determining the sample mass, ensuring all the argon is liberated from the sample given the maximum achievable temperature of the mass spectrometer ovens, and argon loss and non-radiogenic argon in the analysed samples.