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溶剂萃取法分离锂同位素研究进展
引用本文:肖江,贾永忠,姚颖,石成龙,孙进贺,谢绍雷,景燕. 溶剂萃取法分离锂同位素研究进展[J]. 盐湖研究, 2016, 24(3): 62-72
作者姓名:肖江  贾永忠  姚颖  石成龙  孙进贺  谢绍雷  景燕
作者单位:中国科学院青海盐湖研究所,青海 西宁 810008;中国科学院大学,北京 100049,中国科学院青海盐湖研究所,青海 西宁 810008,中国科学院青海盐湖研究所,青海 西宁 810008,中国科学院青海盐湖研究所,青海 西宁 810008,中国科学院青海盐湖研究所,青海 西宁 810008,中国科学院青海盐湖研究所,青海 西宁 810008,中国科学院青海盐湖研究所,青海 西宁 810008
基金项目:国家自然科学盐湖专项基金(U140710047)
摘    要:锂同位素(6Li和7Li)在原子能工业中占据着重要的地位。在众多锂同位素的分离方法和体系中,溶剂萃取法是一种具有较高分离系数,并最有望实现无毒、高效分离的工业生产方法。阐述了溶剂萃取法分离锂同位素的原理,综述了醇类与酮类、烷基膦与膦酸脂类、冠醚类及其它溶剂萃取体系在锂同位素分离中的研究现状及趋势,并展望了溶剂萃取法在锂同位素分离和未来青海、西藏盐湖锂资源高值化利用中的潜在应用前景。

关 键 词:锂同位素  分离  溶剂萃取
收稿时间:2015-05-11
修稿时间:2015-06-25

A Review of Separation of Lithium Isotopes by the Method of Solvent Extraction
Xiao Jiang,Jia Yongzhong,Yao Ying,Shi Chenglong,Sun Jinhe,Xie Shaolei and Jing Yan. A Review of Separation of Lithium Isotopes by the Method of Solvent Extraction[J]. Journal of Salt Lake Research, 2016, 24(3): 62-72
Authors:Xiao Jiang  Jia Yongzhong  Yao Ying  Shi Chenglong  Sun Jinhe  Xie Shaolei  Jing Yan
Affiliation:Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining,Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining
Abstract::The two naturally occurring isotopes of lithium (6Li and 7Li) occupy important roles in the atomic energy industry.Among the methods for the separation of lithium isotopes,solvent extraction is a method which not only have a higher isotope separation factor,but also is the most promising method expected to achieve industrial production with nontoxicity and higher efficient.Hence,in this paper,we simply illustrate the method of solvent extraction separation of lithium isotopes,and summarizes the alcohols and ketones,the alkylphosphines and phosphonates,the crown ethers and the other solvent extraction systems in the separation of lithium isotope.We also prospect its potential applications in separation of lithium isotopes and to develop a high-value utilization of lithium resources in salt lakes of Qinghai and Tibet.
Keywords:Lithium isotopes separation   Solvent extraction   Extraction method   Crown ether   Alcohols   Ketones   Alkylphosphine   Phosphonate
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