Persistent high concentration of ozone during windstorm conditions in southern Korea

Summary Prior to and following the development of a windstorm in the mountainous coastal area of southern Korea, ground level ozone (O₃)-concentrations near Kangnung city, on the lee side of the mountains, show a maximum value at approximately 1300 LST, owing to a photolytic cycle of NO₂–NO–O₃ during the day and a minimum in concentrations at night as a result of the reverse cycle. During the development period of the windstorm, ozone concentrations are generally high all day, and slightly higher during the night. This distribution pattern of ozone is very different from the typical distribution of ozone in the absence of windstorms. High daytime concentrations of ozone during the windstorm are due to both the increase in the amount of ozone from photochemical reactions involving NO_x and the increase in O₃-concentration due to a decrease in the convective boundary layer thickness under the influence of downslope windstorm conditions on the lee-side of the mountains. At night, the windstorm increases in intensity as the westerly winds combine with a katabatic wind blowing downslope toward the surface at the coast. This causes momentum transport of air parcels in the upper levels toward the surface at the coast and the development of internal gravity waves, which generate a hydraulic jump directed upward over the coast and the East sea, thereby reducing to very thin the thickness of the nocturnal surface inversion layer (NSIL). The higher O₃-concentration at night depends mainly upon the shallow NSIL and on some O₃ being transported by the momentum transfer from the upper troposphere toward the ground in windstorm conditions.