Constraints on formation processes of two coarse-grained calcium- aluminum-rich inclusions: A study of mantles,islands and cores

Abstract— Many coarse-grained calcium- aluminum-rich inclusions (CAIs) contain features that are inconsistent with equilibrium liquid crystallization models of origin. Spinel-free islands (SFIs) in spinel-rich cores of Type B CAIs are examples of such features. One model previously proposed for the origin of Allende 5241, a Type B1 CAI containing SFIs, involves the capture and assimilation of xenoliths by a liquid droplet in the solar nebula (El Goresy et al., 1985; MacPherson et al., 1989). This study reports new textural and chemical zoning data from 5241 and identifies previously unrecognized chemical zoning patterns in the melilite mantle and in a SFI. These zoning patterns are identified by large-scale elemental mapping techniques. The compositional zoning is completely independent of, and cross-cuts individual melilite crystals in the mantle, a relation that suggests the mantle was deposited or accreted onto a preexisting core of the inclusion. Lack of correlation with individual mantle crystals also suggests that the mantle totally recrystallized at subsolidus temperatures. Sodium distribution maps demonstrate that most of the Na in 5241 was introduced during the secondary alteration process. Major- and trace-element data from the SFI boundary in a second type B1 CAI, Allende 3529Z, were obtained. The boundary bisects a large fassaite crystal. If the SFI is a relict xenolith, then chemical differences are likely to be present across the boundary. Electron microprobe analysis of the fassaite crystal reveals concentric zoning of Ti, which is unrelated to the SFI boundary, as well as distinct zones enriched in Al and depleted in Ti⁺³. Ion microprobe analyses at the SFI boundary show no significant variation in Ba, Sc, V, Cr, Sr, Zr, Nb and REE in fassaite. There is no evidence that requires the capture of a xenolith in 3529Z. Based on chemical zoning and textural arguments, it is suggested that both of these CAIs formed by a process of partial melting of precursors, which contained either vesicles or spinel-free grains. Allende 5241 shows evidence for vapor condensation and accretion and/or introduction of a second liquid to form the melilite mantle. Chemical zoning patterns in the mantles of the inclusions indicate that 3529Z experienced a higher degree of partial melting than 5241, but it was not high enough to melt spinel or completely melt and homogenize relict fassaite components.