首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Effects of oil expulsion and pressure on nanopore development in highly mature shale: Evidence from a pyrolysis study of the Eocene Maoming oil shale,south China
Institution:1. Oklahoma Geological Survey, 100 E. Boyd St., Rm. N-131, Norman, OK 73019-0628, USA;2. Minerals End Inc., The Woodlands, TX 77381, USA;3. University of Oklahoma, Norman, OK 73019-0628, USA
Abstract:The influence of oil-expulsion efficiency on nanopore development in highly mature shale was investigated by using anhydrous pyrolysis (425–600 °C) on solvent-extracted and non-extracted shales at a pressure of 50 MPa. Additional pyrolysis studies were conducted using non-extracted shales at pressures of 25 and 80 MPa to further characterize the impact of pressure on pore evolution at high maturity. The pore structures of the original shale and relevant artificially matured samples after pyrolysis were characterized by using low-pressure nitrogen and carbon-dioxide adsorption techniques, and gas yields during pyrolysis were measured. The results show that oil-expulsion efficiency can strongly influence gas generation and nanopore development in highly mature shales, as bitumen remained in shales with low oil expulsion efficiency significantly promotes gaseous hydrocarbon generation and nanopore (diameter < 10 nm) development. The evolution of micropores and fine mesopores at high maturity can be divided into two main stages: Stage I, corresponding to wet gas generation (EasyRo 1.2%–2.4%), and Stage II, corresponding to dry gas generation (EasyRo 2.4%–4.5%). For shales with low oil expulsion efficiency, nanopore (diameter < 10 nm) evolution increases rapidly in Stage I, whereas slowly in Stage II, and such difference between two stages may be attributed to the changes of the organic matter (OM)’s mechanical properties. Comparatively, for shales with high oil expulsion efficiency, the evolution grows slightly in Stage I, not as rapidly as shales with low efficiency, and decays in Stage II. The different pore evolution behaviors of these two types of shales are attributed to the contribution of bitumen. However, the evolution of medium–coarse mesopores and macropores (diameter >10 nm) remains flat at high maturation. In addition, high pressure can promote the development of micropores and fine mesopores in highly mature shales.
Keywords:Oil-shale  Anhydrous pyrolysis  Oil expulsion efficiency  Pressure  Nanopore evolution
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号