山东蒙阴金刚石的"似玛瑙状"生长结构及氮、氢杂质分布的不均一性

阴极发光(CL)技术可揭示金刚石生长结构、阶段和过程.利用该技术首次发现蒙阴金刚石中罕见的"似玛瑙状"生长结构,并分析了该典型结构的特征和生长机制.该样品定向切片的傅立叶变换红外光谱(FTIR)微区分析表明,氮、氢杂质分布不均一,从生长中心至边缘,总氮含量和B中心百分数逐渐降低,但变化幅度较小;氢浓度呈不规则振荡,边缘区最高.该生长结构和杂质不均一特点揭示了金刚石生长过程中熔/流体的参与作用和生长条件、环境的复杂性.

Agate-like Structure and Heterogeneities of Nitrogen and Hydrogen Impurities of Diamond in Mengyin, China

The growth structure, period and process of diamond can be revealed by the cathodluminescence (CL) technique. The rare agate-like structure of diamond is first discovered in Mengyin area, Shandong Province, China and its characteristics and genetic mechanism are discussed. The FTIR in-situ analysis of the oriented plate of the diamond shows that there exist heterogeneities of N and H impurities. The total contents of N and percentage of B defects decrease gradually, and the H contents fluctuate irregularly from central to periphery of the diamond. The growth structure and heterogeneities of the impurities indicate participation of melts/fluids and the complexities in growth processes and environments in upper mantle.