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RESEARCH ON THE DETERMINATION OF Pb, Cd, Cu AND Zn IN SEAWATER BY STRIPPING VOLTAMMETRY
引用本文:许清辉,黄江淮,吕荣辉,黄敏芬. RESEARCH ON THE DETERMINATION OF Pb, Cd, Cu AND Zn IN SEAWATER BY STRIPPING VOLTAMMETRY[J]. 海洋学报(英文版), 1984, 3(3): 369-375
作者姓名:许清辉  黄江淮  吕荣辉  黄敏芬
作者单位:Third Institute of Oceanography, National Bureau of Oceanography, Xiamen;Third Institute of Oceanography, National Bureau of Oceanography, Xiamen;Third Institute of Oceanography, National Bureau of Oceanography, Xiamen;Third Institute of Oceanography, National Bureau of Oceanography, Xiamen
摘    要:In this paper, a comparison viral made between the two results of determining Pb, Cd, Cu and Zn in seawater by direct current (tripping voltammetry (DCS) with rotating glass carbon electrode and by differential pulse stripping voltammetry (DPS) with hanging mercury drop electrode (HMDE). By DCS, the range of linear calibration curves obtained was 4×10-3 M-2×10-7M for Cu, Zn and Cd, and 4× 10-9M-2×10-3M for Pb. By using DPS, the range of linear calibration curve was as follows: Cu 0.65-1.9 ppb; Pb 1.0-10 ppb; Zn 0.65-2.0 ppb; Cd 0.02-0.14 ppb. It was found that DCS could be used for determining Pb, Cu, Zn in coastal waters, but it is necessary to add gallium ion to it to eliminate the interference of Cu-Zn inter-metallic compound for determining Zn. The DPS is better for determinig Cd.

收稿时间:1982-09-01
修稿时间:1983-08-10

RESEARCH ON THE DETERMINATION OF Pb, Cd, Cu AND Zn IN SEAWATER BY STRIPPING VOLTAMMETRY
XU QINGHUI,HUANG JIANGHUAI,L,#; RONGHUI and HUANG MINFEN. RESEARCH ON THE DETERMINATION OF Pb, Cd, Cu AND Zn IN SEAWATER BY STRIPPING VOLTAMMETRY[J]. Acta Oceanologica Sinica, 1984, 3(3): 369-375
Authors:XU QINGHUI,HUANG JIANGHUAI,L&#   RONGHUI  HUANG MINFEN
Affiliation:Third Institute of Oceanography, National Bureau of Oceanography, Xiamen
Abstract:In this paper,a comparison viral made between the two results of determining Pb,Cd,Cu and Zn in seawater by direct current(tripping voltammetry(DCS) with rotating glass carbon electrode and by differential pulse stripping voltammetry(DPS) with hanging mercury drop electrode(HMDE).By DCS,the range of linear calibration curves obtained was 4×10-3 M-2×10-7M for Cu,Zn and Cd,and 4×10-9M-2×10-3M for Pb.By using DPS,the range of linear calibration curve was as follows:Cu 0.65-1.9 ppb; Pb 1.0-10 ppb; Zn 0.65-2.0 ppb; Cd 0.02-0.14 ppb.It was found that DCS could be used for determining Pb,Cu,Zn in coastal waters,but it is necessary to add gallium ion to it to eliminate the interference of Cu-Zn inter-metallic compound for determining Zn.The DPS is better for determinig Cd.
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