Episodic mesozoic volcanism in Namibia and Brazil: A K—Ar Isochron study bearing on the opening of the south atlantic

An attempt is made to find a more objective and precise basis for the correlation of volcanics from southwestern Africa and South America than is possible by frequency diagrams of individual K—Ar ages. This leads to a critical appraisal of conventionally calculated K—Ar ages with the conclusion thata priori assumption regarding the isotopic composition of non-radiogenic argon and, hence, the standard atmospheric correction, are no longer tenable.K—Ar isotoopic data on Mesozoic basalts and dolerites from Namibia and Brazil are presented in terms of an isochron model. Plots for cogenetic rocks are unacceptably scattered on a “radiogenic”⁴⁰Ar vs. K diagram, but show a high degree of collinearity on⁴⁰Ar/³⁶Ar diagrams0K/³⁶Ar diagrams. Using the latter plots, a number of isochrons are generated which indicate that Mesozoic volcanism in these regions occured as several discrete episodes of fairly short duration. Effusion of the extensive Serra Geral basalts of Brazil and the Kaoko basalts of Namibia is shown to have occured simultaneeously at 121 m.y.B.P. Basalts from a series of boreholes along the central Parana Basin, as well as a group of dykes from Sao Paulo, yield isochrons of 128 m.y., which coincides with the postulated onset of separation of Africa and South America based on marine magnetic anomalies. Linear dyke swarms along the Namibian seaboard, interpreted as an expression of the earliest rift phase, have an isochron age of 134 m.y. Sills and dykes, mainly from southern Namibia, with isochron ages of 183 m.y. are considered to be the westernmost manifestation of Stormberg volcanism, not necessarily related to rifting. Most of the igneous suites examined have initial⁴⁰Ar/³⁶Ar ratios significantly different from the modern atmospheric value.