The isotopic composition of strontium and oxygen in lavas from St. Helena,South Atlantic

Strontium and oxygen isotope measurements on the alkali basalt-trachyte-phonolite suite of St. Helena show that some of the late-fractionated rocks are enriched in ⁸⁷Sr and depleted in ¹⁸O relative to the older basalts. The data rule out both the formation of the late-fractionated rocks by the partial melting of hydrothermally altered oceanic crust and the contamination of the volcanic rocks by oceanic sediment. It also appears to be incompatible with models based either on the melting of previously fractionated and crystallized liquids in the volcanic pile, or the long-term fractionation of lavas over several millions of years in a sub-volcanic magma chamber.It is concluded that hydrothermal interaction with meteoric water is the most important cause of the ¹⁸O depletion. If the interaction occurred at widely differing temperatures, and involved meteoric and seawaters, it might conceivably have caused both the oxygen and strontium isotope heterogeneities.